A Novel and Simple Synthesis of Ethers of Hydroxypyridines with Hexafluoropropan-2-ol via Diazotization of Aminopyridines and Aminoquinolines Under Acid-Free Conditions / V. D. Filimonov, A. N. Sanzhiev, R. O. Gulyaev [et al.]

Set Level: Chemistry of Heterocyclic CompoundsCoauthor: Filimonov, V. D., Russian chemist, Professor of the TPU, 1945-, Viktor Dmitrievich;Sanzhiev, A. N., chemist, Associate Scientist of Tomsk Polytechnic University, 1993-, Aldar Nikolaevich;Gulyaev, R. O., chemical engineer, Research Engineer of Tomsk Polytechnic University, 1995-, Roman Olegovich;Krasnokutskaya, E. A ., organic chemist, Professor of Tomsk Polytechnic University, Doctor of chemical sciences, 1966-, Elena Aleksandrovna;Bondarev, A. A., Aleksandr AleksandrovichCorporate Author (Secondary): Национальный исследовательский Томский политехнический университет, Инженерная школа новых производственных технологий, Научно-образовательный центр Н. М. КижнераLanguage: английский.Country: США.Abstract: Herein, we report the first example of diazotization of aminopyridines and aminoquinolines with t-BuONO in hexafluoropropan-2-ol in the absence of acids or other initiators. For aminopyridines, this reaction is the first general route toward 2-, 3-, and 4-[(1,1,1,3,3,3-hexafluoropropan-2-yl)oxy]pyridines..Bibliography: [References: 10 tit.].Audience: .Subject: электронный ресурс | труды учёных ТПУ | aminopyridines | aminoquinolines | anilines | ethers | 1,1,1,3,3,3-hexafluoropropan-2-ol | diazotization Online Resources:Click here to access online
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[References: 10 tit.]

Herein, we report the first example of diazotization of aminopyridines and aminoquinolines with t-BuONO in hexafluoropropan-2-ol in the absence of acids or other initiators. For aminopyridines, this reaction is the first general route toward 2-, 3-, and 4-[(1,1,1,3,3,3-hexafluoropropan-2-yl)oxy]pyridines.

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